
The electrical insulation performance of engineering plastic polyamide (nylon) has significant characteristics, but it needs to be comprehensively evaluated in combination with environmental conditions. The specific manifestations are as follows:
1. Advantages of normal insulation
In a dry state, the polar groups of the molecular chain (- CONH -) bind charge migration, and the volume resistivity can reach the forefront of polymer materials. It can withstand conventional low-voltage electric fields (<1000V) and is widely used in electrical components such as circuit breaker casings and wiring terminals.
2. Deadly humidity defect
Polyamide has strong hygroscopicity (saturated water absorption rate>8%), and after water infiltration:
Forming ion conductive channels, reducing volume resistivity by 3 orders of magnitude
The dielectric loss tangent (tan δ) skyrockets, and self ignition occurs due to heating in a high-frequency electric field
Typical failure: Relay nylon gear carbonized due to leakage in humid environment
3. Temperature related characteristics
Low temperature stability: maintaining excellent insulation at -40 ℃, superior to brittle plastics such as PS
High temperature collapse: When the temperature exceeds 120 ℃, the number of thermally excited charge carriers increases dramatically, and the insulation strength drops sharply
4. Direction of Modification Technology
Nanocomposites: Montmorillonite/Silicon Dioxide Build Maze Barrier to Block Moisture Penetration Paths
Blending optimization: Adding polyolefin (PP/PE) to reduce moisture absorption and sacrifice some mechanical strength
Surface metallization: permanent moisture isolation achieved by electroplating zinc nickel layer or coating with fluororesin
5. High frequency application forbidden zone
In a high-frequency electric field at the MHz level:
The relaxation effect of polar molecules triggers a dielectric loss peak, converting energy into thermal energy
Prohibited for high-frequency scenarios such as RF equipment and 5G base station antennas, PTFE or PPO must be used instead
Characteristic | Impact on Electrical Insulation |
Dry-State Performance | Excellent volume resistivity under low-voltage conditions; suitable for housings/connectors. |
Humidity Vulnerability | Water absorption (>8%) drastically reduces resistivity by orders of magnitude; causes leakage/carbonization. |
Temperature Dependency | Stable insulation at cryogenic temperatures; severe degradation above 120°C due to charge carrier activation. |
High-Frequency Limitation | Prohibited in RF/MHz applications due to dielectric loss heating (use PTFE/PPO instead). |
Reinforcement Solutions | Nanoparticles (SiO₂) reduce moisture ingress; metallization/fluorine coatings create moisture barriers. |
Critical Material Selection | • Dry environments: Standard grades• Intermittent moisture: Low-absorption grades (PA12/PA46)• Wet/high-voltage: Switch to PPS/epoxy composites |